Quantum Mechanical Model of the Atom

IMPORTANT

Quantum Mechanical Model of the Atom: Overview

This Topic covers sub-topics such as Heisenberg Uncertainty Principle, Quantum Numbers, Shapes of Orbitals, Schrodinger's Wave Equation, Principal Quantum Number, Azimuthal Quantum Number, Magnetic Quantum Number and, Spin Quantum Number

Important Questions on Quantum Mechanical Model of the Atom

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The total number of atomic orbitals in the fourth energy level of an atom is :

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A 0.66 kg ball is moving with a speed of 100 m/s. The associated wavelength will be   ( h=6.6× 10 34 Js ):

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Which of the following is not permissible arrangement of electrons in an atom?

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The measurement of the electron position if associated with an uncertainty in momentum which is equal to 1× 10 18 gcm s 1 . The uncertainty in electron velocity is,

(mass of an electron is   9× 10 28 g )

                                                                                                                                                                                                                               

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If uncertainty in position and momentum are equal, then uncertainty in velocity is :

                                                                                                                                                                                                                               

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Consider the following sets of quantum numbers :

  n 1 m s
(i) 3 0 0 +12
(ii) 2 2 1 +12
(iii) 4 3 -2 -12
(iv) 1 0 -1 -12
(v) 3 2 3 +12

which of the following sets of quantum number is not possible ?

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The orientation of an atomic orbital is governed by

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Given : The mass of electron is  9.11×1031kg, Planck constant is  6.626×1034Js, the uncertainty involved in the measurement of velocity within a distance of   0.1Å is

                                                                                                                                                                                                                               

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The number of orbitals possible for the following quantum numbers is/are

n=3,  l=2, m=+2

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The position of both, an electron and a helium atom is known within 1.0 nm. Further, the momentum of the electron is known with in 5.0×1026kgms1.The minimum uncertainty in the measurement of the momentum of the helium atom is

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The position of both, an electron and a helium atom is known within 1.0 nm. Further the momentum of the electron is known within    5.0× 10 26 kgm s 1 .  The minimum uncertainty in the measurement of the momentum of the helium atom is

                                                                                                                                                                                                                               

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The number of spherical nodes in 3p orbitals are

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The electron was shown experimentally to have wave properties by

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The relation between nm (nm=the number of permissible values of magnetic quantum number (m)) for a given value of azimuthal quantum number l, is

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State and explain Heisenberg’s uncertainty principle. Hence show that the electron cannot exist inside the nucleus. Given: = 1.054 × 1034𝐽𝑆 𝑚𝑒 = 9.11 × 1031Kg,the radius of the nucleus of any atom is 𝑟 = 1014𝑚.

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What is the maximum number of orbitals that can be identified with the following quantum numbers?
n=3, l=+1, ml=0.

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In hydrogen atom, the degeneracy of the level with energy -RH9 is

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Radial nodes present in 3s and 3p-orbitals are respectively

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For how many orbitals, the quantum numbers n=3,l=2, m=+2 are possible?

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de-Broglie's wavelength of an electron having kinetic energy 2.7×10-23 J is A×10-8 m. Then, what is the value of A?